Electrical properties of Ta/sub 2/O/sub 5/ gate dielectric on strained-Si

High dielectric constant (high-k) thin Ta/sub 2/O/sub 5/ films have been deposited on tensilely strained silicon (strained-Si) layers using a microwave plasma enhanced chemical vapour deposition technique at a low temperature. The deposited Ta/sub 2/O/sub 5/ films show good electrical properties as gate dielectrics and are suitable for microelectronic applications. The feasibility of integration of strained-Si and high-k dielectrics has been demonstrated.     

Influence of state of stress on mixed mode stable crack growth through D16AT aluminium alloy

The stable crack growth through three-point bend (TPB) and stiffened and unstiffened compact tension (CT) specimens of D16AT aluminium alloy has been studied both theoretically and experimentally. The specimen thickness is 8 mm. The variation of load with crack opening displacement, the extent of stable crack growth, the cumulative plastically deformed zone and crack edge profiles have been obtained experimentally. These are also predicted theoretically under the assumption of either a state of plane stress or plane strain using a finite element scheme and the COA criterion. Generally, the experimental results agree well with the predictions based on the plane stress condition. There appears to be no significant variation in size of the experimental cumulative plastic zone across the specimen thickness, thereby indicating that the constraint on the plastic zone does not develop near the mid-thickness region.     

Hole mobility enhancement in strained-Si p-MOSFETs under high vertical field

The growth of a high quality, step-graded lattice-relaxed SiGe buffer layer on a Si(100) substrate is investigated. p-MOSFETs were fabricated on strained-Si grown on top of the above layer. Carrier confinement at the type-II strained-Si/SiGe buffer interface is observed clearly from the device transconductance and C-V measurements. At high vertical field, compared to bulk silicon, the channel mobility of the strained-Si device with x=0.18 is found to be about 40% and 200% higher at 300 K and 77 K respectively. Measurements on transconductance enhancement are also reported. Data at 77 K provide evidence of two channels and a large enhancement of mobility at high transverse field.     

Underpinning-based simultaneous extraction of contiguous sections of a thick coal seam under weak and laminated parting

Around 12.5 m-thick Zero seam of Chirimiri colliery underneath Bartunga hill of M/s South Eastern Coalfield Limited (SECL) was found in two sections; 3.5 m top and 6.0 m bottom section, with a highly laminated 3.0-m-thick parting between the two sections. The laminated parting, comprised of alternate layers of shale, carbonaceous shale, coal and mudstone, was found to be incompetent for safe and clean underground working of both sections. Both top and bottom sections were developed on superimposed pillars along the floor using roof bolts. Based on laboratory testing and investigations on simulated models, an idea of underpinning was conceived for simultaneous depillaring of both the contiguous sections. Taking advantage of presence of openings in the top section, the laminated parting and roof coal band of bottom section was reinforced simultaneously by a full-column grouted cable bolt of suitable length from the floor of the top section. Underpinning consolidated parting stability through reinforcement and provided additional thickness to the critical parting thickness as the roof coal band of the thick bottom section is stitched together with the parting. Maintaining superimposition of workings in the two sections, pillars of both the sections were extracted by splitting and slicing. Splits and slices of the bottom section did not experience roof instability problems due to the presence of the reinforced overlying roof coal band and parting by underpinning. The roof coal of the bottom section was blasted down on retreat. Consolidation of the multi-layered parting by underpinning did not allow separation and collapse of its mudstone/shale layers resulting in clean coal blasted from the roof. Underpinning-based simultaneous depillaring of the contiguous sections proved its technological feasibility and success through field trials.     

Generation of Arylated Quinones by Iron‐Catalyzed Oxidative Arylation of Phenols: Formal Synthesis of Phellodonin,Sarcodonin ε, Leucomelone and Betulinan A

Biologically and pharmaceutically relevant arylated quinones (Quin‐Ar) have been synthesized via direct C H arylation of a variety of phenols using arylboronic acids. An inexpensive, environmentally friendly iron catalyst, ferric sulphate, Fe₂(SO₄)₃, was employed in this operationally simple and efficient method.

     

Ultra-thin graphene edges at the nanowire tips: a cascade cold cathode with two-stage field amplification

A multistage field emitter based on graphene-linked ZnO nanowire array is realized by means of spin-coating a graphene dispersion (reduced graphene oxide) over a nanostructured platform followed by plasma modification. Spin-coating leads to interlinking of graphene sheets between the neighboring nanowires whereas plasma etching in the subsequent step generates numerous ultra-sharp graphene edges at the nanowire tips. The inherent tendency of graphene to lay flat over a plane substrate can easily be bypassed through the currently presented nanostructure platform based technique. The turn-on and threshold field significantly downshifted compared to the individual components in the cascade emitter. Through the facile electron transfer from nanowires to graphene due to band bending at the ZnO-graphene interface together with multistage geometrical field enhancement at both the nanowire and graphene edges remain behind this enriched field emission from the composite cold cathode. This strategy will open up a new direction to integrate the functionalities of both the graphene array and several other inorganic nanostructure array for practical electronic devices.     

Extraction chromatographic methods in the sample preparation sequence for thermal ionization mass spectrometric analysis of plutonium isotopes

A sample preparation sequence for actinide isotopic analysis by thermal ionization mass spectrometry (TIMS) is described that includes column-based extraction chromatography as the first separation step, followed by anion-exchange column separations. The sequence is designed to include a wet ashing step after the extraction chromatography to prevent any leached extractant or oxalic acid eluent reagents from interfering with subsequent separations, source preparation, or TIMS ionization. TEVA resin and DGA resin materials, containing extractants that consist only of C, N, O, and H atoms, were investigated for isolation of plutonium. Radiotracer level studies confirmed expected high yields from column-based separation procedures. Femtogram-level studies were carried out with TIMS detection, using multiple monoisotopic spikes applied sequentially throughout the separation sequence. Pu recoveries were 87% and 86% for TEVA and DGA resin separations, respectively. The Pu recoveries from 400 μL anion-exchange column separation sequences were 89% and 93% for trial sequences incorporating TEVA and DGA resin. Thus, a prior extraction chromatography step in the sequence did not interfere with the subsequent anion-exchange separation when a simple wet ash step was carried out in between these column separations. The average measurement efficiency for Pu, encompassing the chemical separation recoveries and the TIMS ionization efficiency, was 2.73% ± 0.77% (2σ) for the DGA resin trials and 2.67% ± 0.54% for the TEVA resin trials, compared to 3.41% and 2.37% (average 2.89%) for two control trials. These compare with an average measurement efficiency of 2.78% ± 1.70%, n = 33 from process benchmark analyses using Pu spikes processed through a sequence of oxalate precipitation, wet ash, iron hydroxide precipitation, and anion-exchange column separations. We conclude that extraction chromatography can be a viable separation procedure as part of a multistep sequence for TIMS sample preparation.     

Modelling of mode-I stable crack growth under hydrogen assisted stress corrosion cracking

The paper presents a new strategy based on combined analytical and finite element (FE) solution to hydrogen assisted stress corrosion crack growth. The diffusion process is solved analytically through both one-and two-dimensional modelling. These solutions are adopted with two-dimensional FE based cohesive zone model of crack extension study. The results fit well with published experimental data and show improvement over the predictions by full FE approach. The new solution approach helps to reduce time required for simulation/computation. The study has produced a relationship between concentration dependent reduction in cohesive strength and plastic strain rate.